Red pepper extract as eco-friendly corrosion inhibitor for Carbon steel N80 in 1 M HCl: Electrochemical and surface morphological studies
DOI:
https://doi.org/10.56714/bjrs.50.1.9Keywords:
Corrosion, plant inhibitors, polarisation curves, inhibition efficiency, carbon steelAbstract
Four different concentrations of a plant inhibitor (dry red pepper) were created to investigate its effectiveness in preventing corrosion of a N80 carbon steel alloy used in petroleum pipe manufacturing. This was done in a 1M HCl acidic solution at various temperatures using electrochemical techniques and surface analysis. The inhibitor was discovered to be effective and efficient. As inhibitor concentrations rise, inhibition also increases because the protective layer becomes thicker. At a concentration of 200 ppm at a temperature of 298 K, the inhibition efficiency reached 92.69%. Corrosion rate decreases in the presence of the plant inhibitor. Despite the presence of the plant inhibitor, the corrosion rate in the acidic media (HCl 1M) was 15.58 mpy lower than when the inhibitor was absent. It reached 1.138 when it was. This is because of the reduction in the current density of Icorr. The polarisation results showed that the addition of the inhibitor reduced the corrosion current density of the steel. The Carbon N80 corrosion rate ranges from 34.22 µA/cm2 for the sample without inhibitor to 2.5 µA/cm2 for the sample including 200 ppm of inhibitor (C). The polarisation curves and electrochemical investigations suggest that the corrosion inhibitor exhibits both anodic and cathodic inhibition processes, indicating a mixed kind of inhibition. FT-IR technology analysed the inhibitor's chemical composition and revealed the presence of functional groups and heteroatoms. SEM was utilised to locate the inhibitor layer on the carbon steel alloy surface, which serves to prevent corrosion
Downloads
References
C. Verma, E. E. Ebenso, I. Bahadur, and M. A. Quraishi, “An overview on plant extracts as environmental sustainable and green corrosion inhibitors for metals and alloys in aggressive corrosive media,” J. Mol. Liq., vol. 266, pp. 577–590, 2018. Doi:https://doi.org/10.1016/j.molliq.2018.06.110
A. H. Al-moubaraki and I. B. Obot, “Top of the line corrosion : causes , mechanisms , and mitigation using corrosion inhibitors,” Arab. J. Chem., vol. 14, no. 5, p. 103116, 2021, .Doi:https://doi.org/10.1016/j.arabjc.2021.103116
H. T. Obaid, M. Y. Kadhum, and A. S. Abdulnabi, “Quantum Chemical Calculations and Experimental Studies of using Azo Dye as Corrosion Inhibitors for on Carbon Steel in Acidic Medium”. Doi:https://doi.org/10.1016/j.matpr.2021.10.380
Y. T. Al-Janabi, “An overview of corrosion in oil and gas industry: upstream, midstream, and downstream sectors,” Corros. Inhib. oil gas Ind., pp. 1–39, 2020. Doi:https://doi.org/10.1002/9783527822140.ch1
H. M. Abd El-Lateef, S. Shaaban, M. M. Khalaf, A. Toghan, and K. Shalabi, “Synthesis, experimental, and computational studies of water soluble anthranilic organoselenium compounds as safe corrosion inhibitors for J55 pipeline steel in acidic oilfield formation water,” Colloids Surfaces A Physicochem. Eng. Asp., vol. 625, p. 126894, 2021.Doi:https://doi.org/10.1016/j.colsurfa.2021.126894
A. M. Farhan, R. A. Jassim, N. J. Kadhim, W. A. Mehdi, and A. A. Mehde, “Synthesis of Silver Nanoparticles from Malva parviflora extract and effect on Ecto-5’-Nucleotidase (5’-NT), ADA and AMPDA enzymes in sera of patients with arthrosclerosis,” Baghdad Sci. J., vol. 14, no. 4, p. 742, 2017. Doi:http://dx.doi.org/10.21123/bsj.2017.14.4.0742
S. Tanwer and S. K. Shukla, “Recent advances in the applicability of drugs as corrosion inhibitor on metal surface: A review,” Curr. Res. Green Sustain. Chem., vol. 5, p. 100227, 2022. Doi:https://doi.org/10.1016/j.crgsc.2021.100227
R. W. Revie, Corrosion and corrosion control: an introduction to corrosion science and engineering. John Wiley & Sons, 2008.Doi:https://dx.doi.org/10.1036/0071482431
H. Yan, S. Dai, P. Liu, and Y. Zhu, “Synergistic mechanism of ternary green corrosion inhibitors for N80 steel in 20 wt% HCl solution: Encapsulation and transportation of vanillin through micelles formed by ionic liquids,” Corros. Sci., vol. 227, p. 111750, 2024,Doi:https://doi.org/10.1016/j.corsci.2023.111750
M. A. Quraishi, D. S. Chauhan, and F. A. Ansari, “Development of environmentally benign corrosion inhibitors for organic acid environments for oil-gas industry,” J. Mol. Liq., vol. 329, p. 115514, 2021. Doi:https://doi.org/10.1016/j.molliq.2021.115514
A. Sedik et al., “Dardagan Fruit extract as eco-friendly corrosion inhibitor for mild steel in 1 M HCl: Electrochemical and surface morphological studies,” J. Taiwan Inst. Chem. Eng., vol. 107, pp. 189–200, 2020. Doi:https://doi.org/10.1016/j.jtice.2019.12.006
A. Saxena, D. Prasad, and R. Haldhar, “Investigation of corrosion inhibition effect and adsorption activities of Cuscuta reflexa extract for mild steel in 0.5 M H2SO4,” Bioelectrochemistry, vol. 124, pp. 156–164, 2018. Doi:https://doi.org/10.1016/j.bioelechem.2018.07.006
M. Toorani, M. Aliofkhazraei, M. Mahdavian, and R. Naderi, “Superior corrosion protection and adhesion strength of epoxy coating applied on AZ31 magnesium alloy pre-treated by PEO/Silane with inorganic and organic corrosion inhibitors,” Corros. Sci., vol. 178, p. 109065, 2021. Doi:https://doi.org/10.1016/j.corsci.2020.109065
M. Damej et al., “Performance and interaction mechanism of a new highly efficient benzimidazole-based epoxy resin for corrosion inhibition of carbon steel in HCl: A study based on experimental and first-principles DFTB simulations,” J. Mol. Struct., vol. 1273, p. 134232, 2023, Doi:https://doi.org/10.1016/j.molstruc.2022.134232
X. Feng, Q. Yu, B. Li, and J. Kan, “Comparative analysis of carotenoids and metabolite characteristics in discolored red pepper and normal red pepper based on non-targeted metabolomics,” LWT, vol. 153, p. 112398, 2022.Doi:https://doi.org/10.1016/j.lwt.2021.112398
E.-H. Kim et al., “A comparison of the nutrient composition and statistical profile in red pepper fruits (Capsicums annuum L.) based on genetic and environmental factors,” Appl. Biol. Chem., vol. 62, pp. 1–13, 2019. Doi:https://doi.org/10.1186/s13765-019-0456-y
M. Chouaibi, L. Rezig, S. Hamdi, and G. Ferrari, “Chemical characteristics and compositions of red pepper seed oils extracted by different methods,” Ind. Crops Prod., vol. 128, pp. 363–370, 2019. Doi:https://doi.org/10.1016/j.indcrop.2018.11.030
M. H. Yusoff et al., “An Electrochemical evaluation of synthesized coumarin-Azo dyes as potential corrosion inhibitors for mild steel in 1 M Hcl medium,” Int. J. Electrochem. Sci., vol. 15, no. 12, pp. 11742–11756, 2020. Doi:https://doi.org/10.20964/2020.12.43
N. Agyepong, C. Agyare, M. Adarkwa-Yiadom, and S. Y. Gbedema, “Phytochemical investigation and anti-microbial activity of Clausena anisata (Willd), Hook.,” African J. Tradit. Complement. Altern. Med., vol. 11, no. 3, pp. 200–209, 2014.Doi:https://doi.org/10.4314/ajtcam.v11i3.38
B. M. Praveen, B. M. Prasanna, N. M. Mallikarjuna, M. R. Jagadeesh, N. Hebbar, and D. Rashmi, “Investigation of anticorrosive behaviour of novel tert-butyl 4-[(4-methyl phenyl) carbonyl] piperazine-1-carboxylate for carbon steel in 1M HCl,” Heliyon, vol. 7, no. 2, 2021.Doi:https://doi.org/10.1016/j.heliyon.2021.e06090
S. Deng, X. Li, and H. Fu, “Alizarin violet 3B as a novel corrosion inhibitor for steel in HCl, H2SO4 solutions,” Corros. Sci., vol. 53, no. 11, pp. 3596–3602, 2011.Doi:https://doi.org/10.1016/j.corsci.2011.07.003
R. Lopes-Sesenes, G. F. Dominguez-Patiño, J. G. Gonzalez-Rodriguez, and J. Uruchurtu-Chavarin, “Effect of flowing conditions on the corrosion inhibition of carbon steel by extract of buddleia perfoliata,” Int. J. Electrochem. Sci., vol. 8, no. 1, pp. 477–489, 2013.Doi:https://doi.org/10.1016/S1452-3981(23)14035-1
R. H. Tammam, A. M. Fekry, and M. M. Saleh, “Understanding different inhibition actions of surfactants for mild steel corrosion in acid solution,” Int. J. Electrochem. Sci, vol. 11, pp. 1310–1326, 2016.Doi:https://doi.org/10.1016/S1452-3981(23)15923-2
Zheng, L., Landon, J., Matin, N. S., Thomas, G. A., & Liu, K. Corrosion mitigation via a pH stabilization method in monoethanolamine-based solutions for post-combustion CO2 capture. Corrosion Science, 106, 281-292, (2016).Doi:https://doi.org/10.1016/j.corsci.2016.02.013
M. Negache, K. Taibi, N. Souami, H. Bouchemel and R. Belkada: Intermetallics ,36,P.
-80, (2013). Doi:https://doi.org/10.1016/j.intermet.2013.01.001
Singh, A., Kumar Singh, A., & A Quraishi, M. Dapsone: a novel corrosion inhibitor for mild
steel in acid media. The Open Electrochemistry Journal, 2(1), (2010).Doi:https://doi.org/10.2174/1876505X01002010043
A. M. Al-Sabagh, N. G. Kandil, O. Ramadan, N. M. Amer, R. Mansour, and E. A. Khamis, “Novel cationic surfactants from fatty acids and their corrosion inhibition efficiency for carbon steel pipelines in 1 M HCl,” Egypt. J. Pet., vol. 20, no. 2, pp. 47–57, 2011. Doi:https://doi.org/10.1016/j.ejpe.2011.06.007
A. Al Bahir, “Estimation of the performances of creatine and creatinine as eco-friendly corrosion inhibitors for copper in sodium hydroxide solution,” Int. J. Electrochem. Sci., vol. 18, no. 4, p. 100040, 2023.Doi:https://doi.org/10.1016/j.ijoes.2023.100040
M. A. Quraishi, A. Singh, V. K. Singh, D. K. Yadav, and A. K. Singh, “Green approach to corrosion inhibition of mild steel in hydrochloric acid and sulphuric acid solutions by the extract of Murraya koenigii leaves,” Mater. Chem. Phys., vol. 122, no. 1, pp. 114–122, 2010.Doi:https://doi.org/10.1016/j.matchemphys.2010.02.066
A. Toghan et al., “Computational foretelling and experimental implementation of the performance of polyacrylic acid and polyacrylamide polymers as eco-friendly corrosion inhibitors for copper in nitric acid,” Polymers (Basel)., vol. 14, no. 22, p. 4802, 2022. Doi:https://doi.org/10.1016/j.matchemphys.2010.02.066
T. Szauer and A. Brandt, “Adsorption of oleates of various amines on iron in acidic solution,” Electrochim. Acta, vol. 26, no. 9, pp. 1253–1256, 1981. Doi:https://doi.org/10.1016/00134686(81)85107-9
T. Douadi, H. Hamani, D. Daoud, M. Al-Noaimi, and S. Chafaa, “Effect of temperature and hydrodynamic conditions on corrosion inhibition of an azomethine compounds for mild steel in 1 M HCl solution,” J. Taiwan Inst. Chem. Eng., vol. 71, pp. 388–404, 2017. Doi:https://doi.org/10.1016/j.jtice.2016.11.026
V. R. Saliyan and A. V. Adhikari, “Quinolin-5-ylmethylene-3-{[8-(trifluoromethyl) quinolin-4-yl] thio} propanohydrazide as an effective inhibitor of mild steel corrosion in HCl solution,” Corros. Sci., vol. 50, no. 1, pp. 55–61, 2008. https://doi.org/10.1016/j.corsci.2006.06.035
A. K. Singh and M. A. Quraishi, “Effect of 2, 2′ benzothiazolyl disulfide on the corrosion of mild steel in acid media,” Corros. Sci., vol. 51, no. 11, pp. 2752–2760, 2009.Doi:https://doi.org/10.1016/j.corsci.2009.07.011
H. M. Abd El-Lateef, M. Ismael, and I. M. A. Mohamed, “Novel Schiff base amino acid as corrosion inhibitors for carbon steel in CO2-saturated 3.5% NaCl solution: experimental and computational study,” Corros. Rev., vol. 33, no. 1–2, pp. 77–97, 2015. Doi:https://doi.org/10.1515/corrrev20140059
D. S. Chauhan, M. A. J. Mazumder, M. A. Quraishi, and K. R. Ansari, “Chitosan-cinnamaldehyde Schiff base: A bioinspired macromolecule as corrosion inhibitor for oil and gas industry,” Int. J. Biol. Macromol., vol. 158, pp. 127–138, 2020. Doi:https://doi.org/10.1016/j.ijbiomac.2020.04.200
A. Toghan, M. Khairy, M. Huang, and A. A. Farag, “Electrochemical, chemical and theoretical exploration of the corrosion inhibition of carbon steel with new imidazole-carboxamide derivatives in an acidic environment,” Int. J. Electrochem. Sci., vol. 18, no. 3, p. 100072, 2023, Doi:https://doi.org/10.1016/j.ijoes.2023.100072
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2024 J. Basrah Res. (Sci.)
This work is licensed under a Creative Commons Attribution 4.0 International License.
