Study of thermal and some other physical properties of PVA: CuSo4 Polymer Compound
DOI:
https://doi.org/10.56714/bjrs.50.2.14Keywords:
CuSO4. 5H2O, PVA/PVP mixture, Heat Transfer, SEMAbstract
In this study, casting method has been used to create films by mixing hydrated copper sulfate CuSO4.5H2O with three different concentrations 0.5,1 and1.5 wt% with a combination of PVA/PVP in a 1:1 ratio. The three different samples of different concentration of 0.5, 1 and 1.5 have been denoted as case a, b and c respectively. In order to evaluate and confirm the crystalline quality of the final mixture, PPCu(PVA/PVP/CuSO4.5H2O), the required physical measurements were carried out, including x-ray investigations. Also, an FT-IR analysis was used to investigate the structure and chemical composition of the mixture for the three cases. The film's morphology was studied by use of SEM equipment, which showed that the PPCu mixture's particle distribution was uneven. The thermal conductivity of the mixture at different temperatures was measured using the hot disk technique. The results showed significant influence of CuSO4.5H2O concentration on thermal conductivity
Downloads
References
R. Reisfeld, T. Saraidarov, G. Panzer, V. Levchenko, "New optical material europium EDTA complex in polyvinyl pyrrolidone films with fluorescence enhanced by silver plasmons", Opt. Mater. (2011). https://doi.org/10.1016/j.optmat.2011.04.007.
J. Li, H. Li, H. Hu, Y. Zhau, Q. Wang, " Preparation and application of polymer nano-fiber doped with nano-particles", Opt. Mater, (2015). Doi:https://doi.org/10.1016/j.optmat.2014.11.045.
A. M. Abdelghany, E. M. Abdelrazek, S.I. Badr, M. A. Morsi, "Effect of gamma-irradiation on (PEO/PVP)/Au nanocomposite: materials for electrochemical and optical applications", Mater. Des. (2016). Doi: https://doi.org/10.1016/j.matdes.2016.02.082.
S. Mallakpour, V. Behranvand, in: V.K. Thakur, M.K. Thakur, R.K. Gupta (Eds.)," Hybrid Polymer Composite Materials", Woodhead Publishing, pp 263–289, (2017).
M. Hayama, K. I. Yamamoto, F. Kohori, K. Sakai, J. Membr, "How polysulfone dialysis membranes containing polyvinylpyrrolidone achieve excelle biocompatibility?", Sci. 234. pp. 41–49, (2004). Doi:https://doi.org/10.1016/j.memsci.2004.01.020.
N. Bolong, A. F. Ismail, M. R. Salim, "Sustainable Membrane Technology for Energy, Water, and Environment", John Wiley & Sons Inc., New Jersey, pp. 1–10, (2012).
V. G. Kadajji, G.V. Betageri, Polymers 3, 1972–2009, (2011).
M. K. Rama, V. B. S. Achari, V. V. R. N. Rao, A. K. Sharma," Electrical and optical properties of (PEMA/PVC) polymer blend electrolyte doped with NaClO4 ", Polym. Test. , 30, pp. 881–886,(2011). Doi:https://doi.org/10.1016/j.polymertesting.2011.08.010.
T. M. W. J. Bandara, M. A. K. L. Dissanayake, I. Albinsson, B. E. Mellander, "Mobile charge carrier concentration and mobility of a polymer electrolyte containing PEO and Pr4N+I− using electrical and dielectric measurements", Solid State Ion., 189,pp. 63–68, (2011). Doi: https://doi.org/10.1016/j.ssi.2011.03.004.
E. M. Abdelrazek, A. M. Abdelghany, S. I. Badr, M. A. Morsi, "Structural, optical, morphological and thermal properties of PEO/PVP blend containing different concentrations of biosynthesized Au nanoparticles", J. Mater. Res. Technol., 7, pp. 419–431, (2018). Doi: https://doi.org/10.1016/j.jmrt.2017.06.009.
N. S. Schauser, R. Seshadri, R. A. Segalman, "Multivalent ion conduction in solid polymer systems", Mol. Syst. Des. Eng. 4, pp. 263–279,(2019).
A. R. Polu, R. Kumar, " Impedance Spectroscopy and FTIR Studies of PEG-Based Polymer Electrolytes", E-J. Chem.8, pp347–353, (2011). Doi: https://doi.org/10.1155/2011/628790.
V. Manjunatha, K. Subramanya, H. Devendrappa, "Structural optical and electrical conductivity properties of Li2SO4 doped polymer electrolytes", Compos. Interfaces , 21, pp121–131,(2014). Doi: https://doi.org/10.1080/15685543.2013.838850.
V. M. Mohan, P. B. Bhargav, V. Raja, A. K. Sharma, V.V.R.N. Rao," Optical and electrical properties of pure and doped PEO polymer electrolyte films", Soft Mater. , 5, pp33–46, (2007). Doi: https://doi.org/10.1080/15394450701405291.
H. M. Ahmad, S. H. Sabeeh, S. A. Hussen, "Electrical and Optical Properties of PVA/LiI Polymer Electrolyte Films". Asian Trans. Sci. Technol., 1, 2221–4283, (2012).
. B. N. Rao, R. P. Suvarna, "A study on optical properties of poly (ethylene oxide) based polymer electrolyte with different alkali metal iodides", AIP Conf. Proc., 1728, (2016). Doi: 10.1063/1.4946127.
K. Sivaiah, , K.N. Kumar, , V. Naresh, S. Buddhudu,"Structural and Optical Properties of Li+: PVP & Ag+: PVP Polymer Films", Mater. Sci. Appl., 2, pp. 1688–1696, (2011). Doi: 10.4236/msa.2011.211225.
R. Muchakayala, K.K. Kumar, V.V.R.N, Rao, "Studies on electrical and optical properties of PVP:KIO4 complexed polymer electrolyte films, IOP Conf. Ser. Mater. Sci. Eng. , 73(2015).
M. Farid, "Solar energy storage with phase change", J. Sol. Energy Res., 4 (11) (1986).
G. A. Lane, "Solar Heat Storage: Latent Heat Materials", Volume II., (1986). Doi: https://doi.org/10.1201/9781351076746.
V. Morcos, "Investigation of a latent heat thermal energy storage system", Sol. Wind Technol., 7 (2–3),pp. 197–202, (1990). Doi: https://doi.org/10.1016/0741-983X(90)90087-I.
J.-H. Li, G.-E. Zhang, J.-Y. Wang, "Investigation of a eutectic mixture of sodium acetate trihydrate and urea as latent heat storage", Sol. Energy 47 (6),pp.443–445, (1991). Doi: https://doi.org/10.1016/0038-092X(91)90112-A.
M. Himpel, M. Helm, S. Hiebler, C. Schweigler," Long-Term Test Results from a Latent Heat Storage Developed for a Solar Heating and Cooling System", 10.18086/eurosun, (2010). Doi:10.18086/eurosun.2010.16.08.
D. Morrison, S. Abdel-Khalik, "Effects of phase-change energy storage on the performance of air-based and liquid-based solar heating systems", Sol. Energy 20 (1),pp57–67 ,(1978). Doi: https://doi.org/10.1016/0038-092X(78)90141-X.
S. Das, T.K. Dutta, "Mathematical modeling and experimental studies on solar energy storage in a phase change material", Sol. Energy 51 (5),pp.305–312,(1993). Doi: https://doi.org/10.1016/0038-092X(93)90142-B.
V.V. Tyagi, D. Buddhi, "PCM thermal storage in buildings: a state of art, Renew", Sustain. Energy Rev. 11 (6), pp.1146–1166, (2007). Doi: https://doi.org/10.1016/j.rser.2005.10.002.
N. Sarier, E. Onder, "Organic phase change materials and their textile applications: an overview", Thermochim. Acta, 540 7–60, (2012). Doi: https://doi.org/10.1016/j.tca.2012.04.013.
S. A. Salman, A. Ammar, A. Habeeb and A. A. Sallal, Study of Some Thermal Properties of [PVA:PVP] Polymer Blends Films and the Feasibility of a Biotic Application on the (PVA-PVP-Ag) Nano Polymer Composite Solution, "Indian Journal of Natural Sciences , Vol.9 /Issue 52 / February /( 2019).
S. A.Salman,N.A.Bakr, M. R. Jwameer, "Effect of Annealing on the Optical Properties of (PVA-CuCl) Composites", International Letters of Chemistry, Physics and Astronomy, Vol.63, pp.98-105, (2016).Doi: 10.18052/www.scipress.com/ILCPA.63.98.
R. Singh and S. G. Kulkarin, "Morphological and Mechanical Properties of polyvinyl alcohol Doped with Inorganic Fillers", International Journal of Polymeric Materials and Polymeric Biomaterial, Vol.62, No.6 pp.351-357, (2013). Doi: https://doi.org/10.1080/00914037.2012.700288.
P. J. Liu, W. H. Chen, Y. Liu, S. B. Bai and Q. Wang, "Thermal Melt Processing to Prepare Halogen-Free Flame Retardant Polyvinyl Alcohol", Polymer Degradation and Stability, Vol.109, pp.261-269, (2014). Doi: https://doi.org/10.1016/j.polymdegradstab.2014.07.021.
G. R. Tuttle, "Size and Surface Area Dependent Toxicity of Silver Nanoparticles in Zebrafish Embryos (Danio rerio)", Master of Science, Oregon State University,(2013).
G. H. Chan, J. Zhao, E. M. Hicks, G. C. Schatz, R. P. Van Duyne," Plasmonic properties of copper nanoparticles fabricated by nanosphere lithography", Nano Lett., 7, 947–1952(2007).
T. M. D. Dang, T. T. T. Le, E. Fribourg-Blanc, M. C. Dang, "Synthesis and optical properties of copper nanoparticles prepared by a chemical reduction method", Adv. Nat. Sci. Nanosci. Nanotechnol., 2, 1–6, (2011). Doi:10.1088/2043-6262/2/1/015009.
A. N. Pestryakov, V. P. Petranovskii, A. Kryazhov, O. Ozhereliev, N. Pfänder, A. Knop-Gericke, " Study of copper nanoparticles formation on supports of different nature by UV–Vis diffuse reflectance spectroscopy", Chem. Phys. Lett., 385, pp.173–176, (2004). Doi: https://doi.org/10.1016/j.cplett.2003.12.077.
W. Songping, J. Li, N. Jing, Z. Zhenou, L. Song, " Preparation of ultra fine copper–nickel bimetallic powders for conductive thick film", Intermetallics, 15, pp.1316–1321,(2007). Doi: https://doi.org/10.1016/j.intermet.2007.04.001.
E. M. Abdelrazek, A.M. Abdelghany, A.H. Oraby, G.M. Asnag, "Investigation of Mixed Filler Effect on Optical and Structural Properties of PEMA Films" , International Journal of Engineering and Technology, 12, pp. 98-102, (2012).
N. Rajeswari, S. Selvasekarapandian, C. Sanjeeviraja, J. Kawamura, S. Asath, "A study on polymer blend electrolyte based on PVA/ PVP with proton salt" Polym, Bull., Volume 71, pages 1061–1080, (2014). Doi: 10.1007/s00289-014-1111-8.
A. D. Bhagwat1, S. S. Sawant1, C. M. Mahajan, "Facile Rapid Synthesis of Polyaniline (PANI) Nanofibers", J. NANO- ELECTRON. PHYS. Vol. 8 No 1, (2016). Available :http://essuir.sumdu.edu.ua/handle/123456789/44873.
A. MacDiarmid, A. Epstein, "The concept of secondary doping as applied to polyaniline"Synth. Met. 65 No 2-3, 103, (1994). Doi: https://doi.org/10.1016/0379-6779(94)90171-6.
A. H. Ali, H. A. Sultan, Q. M. A. Hassan and C.A. Emshary "Thermal and Nonlinear Optical Properties of Sudan III", Journal of Fluorescence, vol.34, pp 635-653, (2024). Doi: https://doi.org/10.1007/s10895-023-03312-1.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2024 Basrah Researches Sciences
This work is licensed under a Creative Commons Attribution 4.0 International License.
